Polyglyceryl-4 Oleate CAS 71012-10-7
Polyglyceryl-4 Oleate (CAS 71012-10-7) is a plant derived, PEG-free nonionic emulsifier, the oleic acid ester of tetraglycerol, supplied as a golden to amber viscous liquid. Its low HLB makes it a water in oil emulsifier for creams and sun care, a co-emulsifier and pigment wetter, and the ingredient that gives cleansing oils and balms their oil-to-milk rinse. UATChem supplies cosmetic grade Polyglyceryl-4 Oleate in drums and IBCs, with acid value, color and form confirmed on the COA and TDS; send the quantity, packing and destination for a quote.
- CAS: 71012-10-7 (generic polyglyceryl oleate 9007-48-1)
- EC Number: 618-437-6
- INCI Name: Polyglyceryl-4 Oleate
- Type: Nonionic, PEG-free W/O emulsifier
- Source: Plant derived (glycerol and oleic acid)
- Appearance: Golden to amber viscous liquid
- HLB: Low, suited to water in oil systems
- Function: W/O emulsifier, co-emulsifier, pigment wetting, oil-to-milk
- Use: Creams, sun care, color cosmetics, cleansing oils and balms
- Packaging: 25 kg drum; IBC, custom packing available
What Polyglyceryl-4 Oleate Is
Polyglyceryl-4 Oleate is the ester of tetraglycerol, a four-unit polyglycerol, with oleic acid, sold under the INCI name Polyglyceryl-4 Oleate as a golden to amber viscous liquid. As a low HLB, nonionic and PEG-free emulsifier it builds water in oil creams and lotions and works alongside high HLB co-emulsifiers, and the same material wets pigments and turns anhydrous cleansing oils into a milky rinse on contact with water. It is plant derived and fits mild, ethoxylate-free personal care lines. UATChem supplies it as a cosmetic grade liquid, a mixture of polyglycerol oleate esters whose acid value, hydroxyl value and color are reported on the TDS and COA for each lot.
Cosmetics and Personal Care Use
- Water in oil skin care. Primary emulsifier for rich creams, lotions, balms and baby care built on a water in oil base.
- Sun care and color cosmetics. Emulsifies and wets pigments in sunscreens, foundations and makeup while stabilizing the W/O system.
- Cleansing oils and balms. Drives the oil-to-milk transformation, lifting makeup and sunscreen and rinsing off with little greasy after-feel.
- Co-emulsifier and other uses. Paired with high HLB emulsifiers in mixed systems, and used in ointment bases; food grade polyglycerol ester requirements can be discussed.
For mild, plant based surfactant systems the emulsifier is often paired with decyl glucoside, a gentle alkyl polyglucoside used in the same natural personal care lines.
Typical Specifications
Polyglyceryl-4 Oleate is a polyglycerol ester mixture rather than a single pure compound, so acid value, hydroxyl value, saponification value and color vary by grade and are reported on the TDS and COA; the entries below describe the cosmetic grade we supply.
| Parameter | Typical Value |
|---|---|
| Type | Nonionic, PEG-free W/O emulsifier |
| INCI Name | Polyglyceryl-4 Oleate |
| Appearance | Golden to amber viscous liquid |
| HLB | Low, water in oil |
| Source | Plant derived glycerol and oleic acid |
| Quality | Acid value, hydroxyl value, color per TDS |
Packaging, Documents and Ordering
- Supplied in 25 kg drums and IBCs as a viscous liquid; drums and totes stay sealed in a cool place, away from heat and protected from freezing.
- Every lot carries a TDS and COA with acid value, hydroxyl value, color and form, together with an SDS; INCI and cosmetic compliance documents and samples can be discussed at inquiry.
- For a quote, UATChem needs the quantity, packing (drum or IBC) and destination port; mention any food or pharmacopoeia grade requirement up front.
FAQ
Q: What is Polyglyceryl-4 Oleate used for?
A: It is a PEG-free, low HLB nonionic W/O emulsifier for creams and sun care, and gives cleansing oils their milky rinse.
Q: Is Polyglyceryl-4 Oleate plant derived and PEG-free?
A: Yes, it is made from glycerol and oleic acid with no ethoxylation, for plant based, mild and PEG-free care formulas.
Q: What does Polyglyceryl-4 Oleate do in cleansing oils?
A: It self-emulsifies with water, turning oil into a light milk that lifts makeup and sunscreen and rinses without greasy feel.
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